(η4-Cycloocta-1,5-diene)diiodidoplatinum(II)
نویسندگان
چکیده
منابع مشابه
[η5-(Phenylethynyl)cyclopentadienyl](η4-tetraphenylcyclobutadiene)cobalt(I)
In the title compound, [Co(C(13)H(9))(C(28)H(20))], the Co atom is sandwiched between cyclo-penta-dienyl and cyclo-butadienyl rings that are inclined at a dihedral angle of 2.6 (3)°. The four phenyl rings are tilted with respect to the cyclo-butadienyl plane so that the C(4)Ph(4) unit constitutes a four-bladed propeller. The phenyl ring of the phenyl-alkyne substituent is inclined to the cyclo-...
متن کامل(η4-Cyclooctatetraene)(η8-cyclooctatetraene)iodidotantalum(V)
The title complex, [Ta(η(4)-C8H8)(η(8)-C8H8)I], lies across a crystallographic mirror plane that includes the Ta(V) atom and the iodide ligand. One cyclo-octa-tetra-ene (cot) ring is η(4)-coordinating and is bis-ected by the mirror plane. The fold angle between the plane of the coordinating butadiene portion and the middle plane of the ring is 27.4 (4)°. An additional minor fold angle of 9.3 (7...
متن کامل(η4-s-cis-1,3-Butadiene)tetracarbonylchromium(0)
In the title complex, [Cr(C(4)H(6))(CO)(4)], the Cr(0) atom shows a distorted octa-hedral environment from four C atoms of the carbonyl ligands and the two π-bonds of the s-cis-1,3-butadiene ligand. The complex has an approximate non-crystallographic mirror symmetry m passing through the chromium atom, two carbonyl ligands and the mid-point of the central C-C bond of the s-cis-1,3-butadiene lig...
متن کامل(η4-Cycloocta-1,5-diene)diiodidoplatinum(II)
The monoclinic title complex, [PtI(2)(C(8)H(12))], characterized by a twisted cyclo-octa-diene ring, is similar to its Cl and Br ortho-rhom-bic homologues. The observed Pt-I bond distances of 2.6094 (5) and 2.6130 (5) Å are in the expected range for PtI(2) complexes. The C=C double bonds in the mol-ecule differ significantly [1.373 (10) and 1.403 (10) Å]. As expected for a platinum(II) complex,...
متن کاملBis(acrylonitrile-κN)dichlorido(η4-cycloocta-1,5-diene)ruthenium(II)
In the title complex, [RuCl(2)(C(8)H(12))(C(3)H(3)N)(2)], the metal ion is coordinated to centers of each of the double bonds of the cyclo-octa-1,5-diene ligand, to two chloride ions (in cis positions) and to two N-atom donors from two acrylonitrile mol-ecules that complete the coordination sphere for the neutral complex. The coordination about the Ru(II) atom can thus be considered octa-hedral...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2009
ISSN: 1600-5368
DOI: 10.1107/s1600536809029997